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The electrons in an atom are in continuous and constant motion in shells around the nucleus, represented by capital letters K,L, M,N, etc. The K shell is the innermost and the nearest to the nucleus followed by the L-shell, then the M-shell the N-shell etc. Each shell is at the energy level represented by the principal quantum number n. The K-shell is in the first energy level, where n=1. It has the lowest energy, and hence the most stable shell. The L-shell is in the second energy level n=2; the M-shell is in the third energy level n=3, while the N-shell is in the fourth energy level, n=4.

ShellKLMN
Energy Level(n)1234

SubShells & Atomic Orbitals

Each Shell has one or more subshells which are at energy sublevels represented by small letters of the alphabets s,p,d, or f. The number of sublevels in a main shell equals the value of n, the energy level hence

  • K-shell(n=1), has only one subshell, 1s
  • L-shell(n=2) has only two subshell 2s, 2p
  • M-shell(n=3) has only three subshell 3s, 3p, 3d
  • N-shell(n=4) has four subshell 4s, 4p. 4d, 4f

Each subshell has one or more atomic orbitals. An atomic orbital is a region around the nucleus where electrons are most likely to be found.

  • An s-subshell has one orbital called s-orbital
  • A p-subshell has three orbitals called p-orbitals
  • A d-subshell has five orbitals called d-orbitals
  • An f-subshell has seven orbitals called f-orbitals
Subshellsspdf
Number of orbitals1357
  • An s-orbital is spherical in shape, and symmetrical about the nucleus
  • A p-orbital has a dumbbell shape like figure eight
  • An orbital can accommodate a maximum of two electrons
Energy Level
(n)
(Shell)
Sub-Shell
n
No of orbitals
n2

(Total)
No of electrons per subshellMaximum Electrons per Shell 2n2
K1s1(1)22
L2s
2p
1
3(4)
2
6
8
M3s
3p
3d
1
3
5(9)
2
6
10
18
N4s
4p
4d
4f
1
3
5
7(16)
2
6
10
14
32

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